Applied thermodynamics of fluids / edited by A.R.H. Goodwin, J.V. Sengers, C.J. Peters [E-Book]
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Full text |
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Personal Name(s): | Goodwin, A. R. H. |
Sengers, J. V. / Peters, Cor J. | |
Imprint: |
Cambridge :
RSC Pub.,
c2010
|
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xxiii, 509 pages : illustrations |
Note: |
englisch |
Subject (LOC): |
- Machine generated contents note:
- ch. 1
- Introduction /
- J. Peters
- References
- ch. 2
- Fundamental Considerations /
- Cor J. Peters
- 2.1.
- Introduction
- 2.2.
- Basic Thermodynamics
- 2.2.1.
- Homogeneous Functions
- 2.2.2.
- Thermodynamic Properties from Differentiation of Fundamental Equations
- 2.3.
- Deviation Functions
- 2.3.1.
- Residual Functions
- 2.3.2.
- Evaluation of Residual Functions
- 2.4.
- Mixing and Departure Functions
- 2.4.1.
- Departure Functions with Temperature, Molar Volume and Composition as the Independent Variables
- 2.4.2.
- Departure Functions with Temperature, Pressure and Composition as the Independent Variables
- 2.5.
- Mixing and Excess Functions
- 2.6.
- Partial Molar Properties
- 2.7.
- Fugacity and Fugacity Coefficients
- 2.8.
- Activity Coefficients
- 2.9.
- The Phase Rule
- 2.10.
- Equilibrium Conditions
- 2.10.1.
- Phase Equilibria
- 2.10.2.
- Chemical Equilibria
- 2.11.
- Stability and the Critical State
- 2.11.1.
- Densities and Fields
- 2.11.2.
- Stability.
- 2.11.3.
- Critical State
- References
- ch. 3
- The Virial Equation of State /
- J. P. Martin Trusler
- 3.1.
- Introduction
- 3.1.1.
- Temperature Dependence of the Virial Coefficients
- 3.1.2.
- Composition Dependence of the Virial Coefficients
- 3.1.3.
- Convergence of the Virial Series
- 3.1.4.
- The Pressure Series
- 3.2.
- Theoretical Background
- 3.2.1.
- Virial Coefficients of Hard-Core-Square-Well Molecules
- 3.3.
- Thermodynamic Properties of Gases
- 3.3.1.
- Perfect-gas and Residual Properties
- 3.3.2.
- Helmholtz Energy and Gibbs Energy
- 3.3.3.
- Perfect-Gas Properties
- 3.3.4.
- Residual Properties
- 3.4.
- Estimation of Second and Third Virial Coefficients
- 3.4.1.
- Application of Intermolecular Potential-energy Functions
- 3.4.2.
- Corresponding-states Methods
- References
- ch. 4
- Cubic and Generalized van der Waals Equations of State /
- Ioannis G. Economou
- 4.1.
- Introduction
- 4.2.
- Cubic Equation of State Formulation
- 4.2.1.
- The van der Waals Equation of State (1873)
- 4.2.2.
- The Redlich and Kwong Equation of State (1949).
- 4.2.3.
- The Soave, Redlich and Kwong Equation of State (1972)
- 4.2.4.
- The Peng and Robinson Equation of State (1976)
- 4.2.5.
- The Patel and Teja (PT) Equation of State (1982)
- 4.2.6.
- The α Parameter
- 4.2.7.
- Volume Translation
- 4.2.8.
- The Elliott, Suresh and Donohue (ESD) Equation of State (1990)
- 4.2.9.
- Higher-Order Equations of State Rooted to the Cubic Equations of State
- 4.2.10.
- Extension of Cubic Equations of State to Mixtures
- 4.3.
- Applications
- 4.3.1.
- Pure Components
- 4.3.2.
- Oil and Gas Industry
- Hydrocarbons and Petroleum Fractions
- 4.3.3.
- Chemical Industry
- Polar and Hydrogen Bonding Fluids
- 4.3.4.
- Polymers
- 4.3.5.
- Transport Properties
- 4.4.
- Conclusions
- References
- ch. 5
- Mixing and Combining Rules /
- Stanley I. Sandler
- 5.1.
- Introduction
- 5.2.
- The Virial Equation of State
- 5.3.
- Cubic Equations of State
- 5.3.1.
- Mixing Rules
- 5.3.2.
- Combining Rules
- 5.3.3.
- Non-Quadratic Mixing and Combining Rules
- 5.3.4.
- Mixing Rules that Combine an Equation of State with an Activity-Coefficient Model.
- 5.4.
- Multi-Parameter Equations of State
- 5.4.1.
- Benedict, Webb, and Rubin Equation of State
- 5.4.2.
- Generalization with the Acentric Factor
- 5.4.3.
- Helmholtz-Function Equations of State
- 5.5.
- Mixing Rules for Hard Spheres and Association
- 5.5.1.
- Mixing and Combining Rules for SAFT
- 5.5.2.
- Cubic Plus Association Equation of State
- References
- ch. 6
- The Corresponding-States Principle /
- James F. Ely
- 6.1.
- Introduction
- 6.2.
- Theoretical Considerations
- 6.3.
- Determination of Shape Factors
- 6.3.1.
- Other Reference Fluids
- 6.3.2.
- Exact Shape Factors
- 6.3.3.
- Shape Factors from Generalized Equations of State
- 6.4.
- Mixtures
- 6.4.1.
- van der Waals One-Fluid Theory
- 6.4.2.
- Mixture Corresponding-States Relations
- 6.5.
- Applications of Corresponding-States Theory
- 6.5.1.
- Extended Corresponding-States for Natural Gas Systems
- 6.5.2.
- Extended Lee-Kesler
- 6.5.3.
- Generalized Crossover Cubic Equation of State
- 6.6.
- Conclusions
- References
- ch. 7
- Thermodynamics of Fluids at Meso and Nano Scales /
- Christopher E. Bertrand.
- 7.1.
- Introduction
- 7.2.
- Thermodynamic Approach to Meso-Heterogeneous Systems
- 7.2.1.
- Equilibrium Fluctuations
- 7.2.2.
- Local Helmholtz Energy
- 7.3.
- Applications of Meso-Thermodynamics
- 7.3.1.
- Van der Waals Theory of a Smooth Interface
- 7.3.2.
- Polymer Chain in a Dilute Solution
- 7.3.3.
- Building a Nanoparticle Through Self Assembly
- 7.3.4.
- Modulated Fluid Phases
- 7.4.
- Meso-Thermodynamics of Criticality
- 7.4.1.
- Critical Fluctuations
- 7.4.2.
- Scaling Relations
- 7.4.3.
- Near-Critical Interface
- 7.4.4.
- Divergence of Tolman's Length
- 7.5.
- Competition of Meso-Scales
- 7.5.1.
- Crossover to Tricriticality in Polymer Solutions
- 7.5.2.
- Tolman's Length in Polymer Solutions
- 7.5.3.
- Finite-size Scaling
- 7.6.
- Non-Equilibrium Meso-Thermodynamics of Fluid Phase Separation
- 7.6.1.
- Relaxation of Fluctuations
- 7.6.2.
- Critical Slowing Down
- 7.6.3.
- Homogeneous Nucleation
- 7.6.4.
- Spinodal Decomposition
- 7.7.
- Conclusion
- References
- ch. 8
- SAFT Associating Fluids and Fluid Mixtures /
- Amparo Galindo.
- 8.1.
- Introduction
- 8.2.
- Statistical Mechanical Theories of Association and Wertheim's Theory
- 8.3.
- SAFT Equations of State
- 8.3.1.
- SAFT-HS and SAFT-HR
- 8.3.2.
- Soft-SAFT
- 8.3.3.
- SAFT-VR
- 8.3.4.
- PC-SAFT
- 8.3.5.
- Summary
- 8.4.
- Extensions of the SAFT Approach
- 8.4.1.
- Modelling the Critical Region
- 8.4.2.
- Polar Fluids
- 8.4.3.
- Ion-Containing Fluids
- 8.4.4.
- Modelling Inhomogeneous Fluids
- 8.4.5.
- Dense Phases: Liquid Crystals and Solids
- 8.5.
- Parameter Estimation: Towards more Predictive Approaches
- 8.5.1.
- Pure-component Parameter Estimation
- 8.5.2.
- Use of Quantum Mechanics in SAFT Equations of State
- 8.5.3.
- Unlike Binary Intermolecular Parameters
- 8.6.
- SAFT Group-Contribution Approaches
- 8.6.1.
- Homonuclear Group-Contribution Models in SAFT
- 8.6.2.
- Heteronuclear Group Contribution Models in SAFT
- 8.7.
- Concluding Remarks
- References
- ch. 9
- Polydisperse Fluids /
- Dieter Browarzik
- 9.1.
- Introduction
- 9.2.
- Influence of Polydispersity on the Liquid + Liquid Equilibrium of a Polymer Solution.
- 9.3.
- Approaches to Polydispersity
- 9.3.1.
- The Pseudo-component Method
- 9.3.2.
- Continuous Thermodynamics
- 9.4.
- Application to Real Systems
- 9.4.1.
- Polymer Systems
- 9.4.2.
- Petroleum Fluids, Asphaltenes, Waxes and Other Applications
- 9.5.
- Conclusions
- References
- ch. 10
- Thermodynamic Behaviour of Fluids near Critical Points /
- Mikhail A. Anisimov
- 10.1.
- Introduction
- 10.2.
- General Theory of Critical Behaviour
- 10.2.1.
- Scaling Fields, Critical Exponents, and Critical Amplitudes
- 10.2.2.
- Parametric Equation of State
- 10.3.
- One-Component Fluids
- 10.3.1.
- Simple Scaling
- 10.3.2.
- Revised Scaling
- 10.3.3.
- Complete Scaling
- 10.3.4.
- Vapour-Liquid Equilibrium
- 10.3.5.
- Symmetric Corrections to Scaling
- 10.4.
- Binary Fluid Mixtures
- 10.4.1.
- Isomorphic Critical Behaviour of Mixtures
- 10.4.2.
- Incompressible Liquid Mixtures
- 10.4.3.
- Weakly Compressible Liquid Mixtures
- 10.4.4.
- Compressible Fluid Mixtures
- 10.4.5.
- Dilute Solutions
- 10.5.
- Crossover Critical Behaviour
- 10.5.1.
- Crossover from Ising-like to Mean-Field Critical Behaviour.
- 10.5.2.
- Effective Critical Exponents
- 10.5.3.
- Global Crossover Behaviour of Fluids
- 10.6.
- Discussion
- Acknowledgements
- References
- ch. 11
- Phase Behaviour of Ionic Liquid Systems /
- Cor J. Peters
- 11.1.
- Introduction
- 11.2.
- Phase Behaviour of Binary Ionic Liquid Systems
- 11.2.1.
- Phase Behaviour of (Ionic Liquid + Gas Mixtures)
- 11.2.2.
- Phase Behaviour of (Ionic Liquid + Water)
- 11.2.3.
- Phase Behaviour of (Ionic Liquid + Organic)
- 11.3.
- Phase Behaviour of Ternary Ionic Liquid Systems
- 11.3.1.
- Phase Behaviour of (Ionic Liquid + Carbon Dioxide + Organic)
- 11.3.2.
- Phase Behaviour of (Ionic Liquid + Aliphatic + Aromatic)
- 11.3.3.
- Phase Behaviour of (Ionic Liquid + Water + Alcohol)
- 11.3.4.
- Phase Behaviour of Ionic Liquid Systems with Azeotropic Organic Mixtures
- 11.4.
- Modeling of the Phase Behaviour of Ionic Liquid Systems
- 11.4.1.
- Molecular Simulations
- 11.4.2.
- Excess Gibbs-energy Methods
- 11.4.3.
- Equation of State Modeling
- 11.4.4.
- Quantum Chemical Methods
- References
- ch. 12
- Multi-parameter Equations of State for Pure Fluids and Mixtures /
- Roland Span.
- 12.1.
- Introduction
- 12.2.
- The Development of a Thermodynamic Property Formulation
- 12.3.
- Fitting an Equation of State to Experimental Data
- 12.3.1.
- Recent Nonlinear Fitting Methods
- 12.4.
- Pressure-Explicit Equations of State
- 12.4.1.
- Cubic Equations
- 12.4.2.
- The Benedict-Webb-Rubin Equation of State
- 12.4.3.
- The Bender Equation of State
- 12.4.4.
- The Jacobsen-Stewart Equation of State
- 12.4.5.
- Thermodynamic Properties from Pressure-Explicit Equations of State
- 12.5.
- Fundamental Equations
- 12.5.1.
- The Equation of Keenan, Keyes, Hill, and Moore
- 12.5.2.
- The Equations of Haar, Gallagher, and Kell
- 12.5.3.
- The Equation of Schmidt and Wagner
- 12.5.4.
- Reference Equations of Wagner
- 12.5.5.
- Technical Equations of Span and of Lemmon
- 12.5.6.
- Recent Equations of State.
- Note continued
- 13.6.
- Concluding Remarks
- References
- ch. 14
- Applied Non-Equilibrium Thermodynamics /
- Dick Bedeaux
- 14.1.
- Introduction
- 14.1.1.
- A Systematic Thermodynamic Theory for Transport
- 14.1.2.
- On the Validity of the Assumption of Local Equilibrium
- 14.1.3.
- Concluding remarks
- 14.2.
- Fluxes and Forces from the Second Law of Thermodynamics
- 14.2.1.
- Continuous phases
- 14.2.2.
- Maxwell-Stefan Equations
- 14.2.3.
- Discontinuous Systems
- 14.2.4.
- Concluding Remarks
- 14.3.
- Chemical Reactions
- 14.3.1.
- Thermal Diffusion in a Reacting System
- 14.3.2.
- Mesoscopic Description Along the Reaction Coordinate
- 14.3.3.
- Heterogeneous Catalysis
- 14.3.4.
- Concluding Remarks
- 14.4.
- The Path of Energy-Efficient Operation
- 14.4.1.
- An Optimisation Procedure
- 14.4.2.
- Optimal Heat Exchange
- 14.4.3.
- The Highway Hypothesis for a Chemical Reactor
- 14.4.4.
- Energy-Efficient Production of Hydrogen Gas
- 14.4.
- Conclusions
- References.