This title appears in the Scientific Report : 2014 

Influence of the Ba$^{2+}$/Sr$^{2+}$ Content and Oxygen Vacancies on the Stability of Cubic Ba$_{x}$Sr$_{1-x}$Co$_{0.75}$Fe$_{0.25}$O$_{3−δ}$
Lumeij, M (Corresponding Author)
Gilleßen, M. / Bouwmeester, H. / Markus, Torsten / Mayer, M. / Barthel, Juri / Roitsch, Stefan / Dronskowski, R.
Werkstoffstruktur und -eigenschaften; IEK-2
Mikrostrukturforschung; PGI-5
Physical chemistry, chemical physics, 16 (2014) S. 1333-1338
Cambridge RSC Publ. 2014
10.1039/c3cp53958j
Journal Article
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Please use the identifier: http://dx.doi.org/10.1039/c3cp53958j in citations.
We present a theoretical and experimental study on the influence ofthe Ba/Sr and Co/Fe ratios as well as the oxygen-non-stoichiometry onthe stability of Ba0.5Sr0.5Co0.8Fe0.2O3d (BSCF). Thin-layer depositionsare analysed by looking at TEM images and EDX spectra. Bondanalyticalcalculations are performed to explain the stability differencebetween hexagonal and cubic BSCF. Finally, annealing experimentsanalysed using XRD give an insight into the differences of phasefractiongrowth with respect to the Ba/Sr ratio.