This title appears in the Scientific Report : 2015 

Total Synthesis of Solandelactones A and B
Eichenauer, Nils C.
Nordschild, Anja C. M. / Bischop, Martina / Schumacher, Dominik / Mackwitz, Marcel K. W. / Tschersich, Roxanne / Wilhelm, Thorsten / Pietruszka, Jörg (Corresponding author)
Institut für Bioorganische Chemie (HHUD); IBOC
Biotechnologie Technische und administrative Infrastruktur IBG-1; IBG-1-TA
European journal of organic chemistry, 2015 (2015) 25, S. 5620 - 5632
Weinheim Wiley-VCH Verl. 2015
Journal Article
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The total synthesis of solandelactones A and B is presented. The eastern cyclopropyl moiety was prepared following an exceptionally short chemoenzymatic approach whereas enantioselective synthesis of the western side-chain relied on the application of diastereomerically pure allyl boronates. The natural products solandelactones A and B were isolated in good overall yields following convergence of each eastern and western element by application of the Nozaki–Hiyama–Kishi reaction.