This title appears in the Scientific Report : 2016 

Influence of hydrophobic treatment on the structure of compressed gas diffusion layers
Tötzke, C. (Corresponding author)
Gaiselmann, G. / Osenberg, M. / Arlt, T. / Markötter, H. / Hilger, A. / Kupsch, A. / Müller, B. R. / Schmidt, V. / Lehnert, Werner / Manke, I.
Elektrochemische Verfahrenstechnik; IEK-3
Journal of power sources, 324 (2016) S. 625 - 636
New York, NY [u.a.] Elsevier 2016
10.1016/j.jpowsour.2016.05.118
Journal Article
Fuel Cells
Please use the identifier: http://dx.doi.org/10.1016/j.jpowsour.2016.05.118 in citations.
Carbon fiber based felt materials are widely used as gas diffusion layer (GDL) in fuel cells. Their transport properties can be adjusted by adding hydrophobic agents such as polytetrafluoroethylene (PTFE). We present a synchrotron X-ray tomographic study on the felt material Freudenberg H2315 with different PTFE finishing. In this study, we analyze changes in microstructure and shape of GDLs at increasing degree of compression which are related to their specific PTFE load. A dedicated compression device mimicking the channel-land pattern of the flowfield is used to reproduce the inhomogeneous compression found in a fuel cell. Transport relevant geometrical parameters such as porosity, pore size distribution and geometric tortuosity are calculated and consequences for media transport discussed. PTFE finishing results in a marked change of shape of compressed GDLs: surface is smoothed and the invasion of GDL fibers into the flow field channel strongly mitigated. Furthermore, the PTFE impacts the microstructure of the compressed GDL. The number of available wide transport paths is significantly increased as compared to the untreated material. These changes improve the transport capacity liquid water through the GDL and promote the discharge of liquid water droplets from the cell.