This title appears in the Scientific Report : 2004 

The instability of vicinal electrode surfaces against step bunching II : theory
Ibach, H.
Schmickler, W.
Institut für Grenzflächen und Vakuumtechnologien; ISG-3
Surface science, 573 (2004) S. 24 - 31
Amsterdam Elsevier 2004
24 - 31
10.1016/j.susc.2004.04.058
Journal Article
Kondensierte Materie
Surface Science 573
J
Please use the identifier: http://dx.doi.org/10.1016/j.susc.2004.04.058 in citations.
It is shown that vicinal surfaces with a regular step array in contact with an electrolyte are intrinsically unstable against a phase separation into areas of flat terraces and areas of step bunches. The effect is caused by the step dipole moment which lowers the potential of zero charge (pzc) of stepped surfaces. Specific calculations performed for vicinal surfaces of silver are qualitatively in keeping with experimental observations. Step bunching is likewise expected for vicinal surfaces of gold and platinum. (C) 2004 Elsevier B.V. All rights reserved.