This title appears in the Scientific Report :
2003
Please use the identifier:
http://hdl.handle.net/2128/2435 in citations.
Please use the identifier: http://dx.doi.org/10.1021/ol034415b in citations.
Benzaldehyde lyase-catalyzed enantioselective carboligation of aromatic aldehydes with mono- and dimethoxy acetaldehyde
Benzaldehyde lyase-catalyzed enantioselective carboligation of aromatic aldehydes with mono- and dimethoxy acetaldehyde
[reaction: see text] Benzaldehyde lyase from the Pseudomonas fluorescens catalyzes the reaction of aromatic aldehydes with methoxy and dimethoxy acetaldehyde and furnishes (R)-2-hydroxy-3-methoxy-1-arylpropan-1-one and (R)-2-hydroxy-3,3-dimethoxy-1-arylpropan-1-one in high yields and enantiomeric ex...
Saved in:
Personal Name(s): | Demir, A. S. |
---|---|
Sesenoglu, Ö. / Dünkelmann, P. / Müller, M. | |
Contributing Institute: |
Biotechnologie 2; IBT-2 |
Published in: | Organic letters, 5 (2003) S. 2047 - 2050 |
Imprint: |
Washington, DC
ACS
2003
|
Physical Description: |
2047 - 2050 |
PubMed ID: |
12790525 |
DOI: |
10.1021/ol034415b |
Document Type: |
Journal Article |
Research Program: |
Biotechnologie |
Series Title: |
Organic Letters
5 |
Subject (ZB): | |
Link: |
Get full text OpenAccess |
Publikationsportal JuSER |
Please use the identifier: http://dx.doi.org/10.1021/ol034415b in citations.
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520 | |a [reaction: see text] Benzaldehyde lyase from the Pseudomonas fluorescens catalyzes the reaction of aromatic aldehydes with methoxy and dimethoxy acetaldehyde and furnishes (R)-2-hydroxy-3-methoxy-1-arylpropan-1-one and (R)-2-hydroxy-3,3-dimethoxy-1-arylpropan-1-one in high yields and enantiomeric excess via acyloin linkage. Aromatic aldehydes and benzoins are converted into enamine-carbanion-like intermediates prior to carboligation. | ||
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650 | 2 | |2 MeSH |a Aldehyde-Lyases: chemistry | |
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