This title appears in the Scientific Report : 2003 

Electrosorption of Br and Cl on Ag(1 0 0) - Experiments and Computer Simulations
Hamad, I. A.
Wandlowski, T. / Brown, G. / Rikvold, P. A.
Institut für Grenzflächen und Vakuumtechnologien; ISG-3
Journal of electroanalytical chemistry, 554-555 (2003) S. 211 - 219
New York, NY [u.a.] Elsevier 2003
211 - 219
Journal Article
Materialien, Prozesse und Bauelemente für die Mikro- und Nanoelektronik
Journal of Electroanalytical Chemistry 554-555
Please use the identifier: in citations.
We present chronocoulometry experiments and equilibrium Monte Carlo simulations for the electrosorption of Br and Cl on Ag(1 0 0) single-crystal electrode surfaces. Two different methods are used to calculate the long-range part of the adsorbate-adsorbate interactions. The first method is a truncated-sum approach, while the second is a mean-field-enhanced truncated-sum approach. To compare the two methods, the resulting isotherms are fit to experimental adsorption isotherms, assuming both a constant electrosorption valency gamma and also a coverage-dependent gamma. While a constant gamma fits the Br/Ag(1 0 0) well, a coverage-dependent or potential-dependent gamma is needed for Cl/Ag(1 0 0). (C) 2003 Elsevier B.V. All rights reserved.