This title appears in the Scientific Report :
2003
Please use the identifier:
http://hdl.handle.net/2128/1622 in citations.
Please use the identifier: http://dx.doi.org/10.1103/PhysRevLett.91.165701 in citations.
Surface Freezing and a Two-Step Pathway of the Isotropic-Smectic Phase Transition in Colloidal Rods
Surface Freezing and a Two-Step Pathway of the Isotropic-Smectic Phase Transition in Colloidal Rods
We study the kinetics of the isotropic-smectic phase transition in a colloidal rod/polymer mixture by visualizing individual smectic layers. First, we show that the bulk isotropic-smectic phase transition is preceded by a surface freezing transition in which a quasi-two-dimensional smectic phase wet...
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Personal Name(s): | Dogic, Z. |
---|---|
Contributing Institute: |
Weiche Materie; IFF-WM |
Published in: | Physical review letters, 91 (2003) S. 165701-1 - 165701-4 |
Imprint: |
College Park, Md.
APS
2003
|
Physical Description: |
165701-1 - 165701-4 |
DOI: |
10.1103/PhysRevLett.91.165701 |
Document Type: |
Journal Article |
Research Program: |
Kondensierte Materie |
Series Title: |
Physical Review Letters
91 |
Subject (ZB): | |
Link: |
Get full text OpenAccess |
Publikationsportal JuSER |
Please use the identifier: http://dx.doi.org/10.1103/PhysRevLett.91.165701 in citations.
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520 | |a We study the kinetics of the isotropic-smectic phase transition in a colloidal rod/polymer mixture by visualizing individual smectic layers. First, we show that the bulk isotropic-smectic phase transition is preceded by a surface freezing transition in which a quasi-two-dimensional smectic phase wets the isotropic-nematic interface. Next, we identify a two-step kinetic pathway for the formation of a bulk smectic phase. In the first step a metastable isotropic-nematic interface is formed. This interface is wetted by the surface-induced smectic phase. In the subsequent step, smectic layers nucleate at this surface phase and grow into the isotropic bulk phase. | ||
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