This title appears in the Scientific Report :
2007
Please use the identifier:
http://dx.doi.org/10.1016/j.jorganchem.2007.06.009 in citations.
[18F]fluorophenyl organometallics as intermediates of no-carrier-added 18F-fluoroarylation reactions
[18F]fluorophenyl organometallics as intermediates of no-carrier-added 18F-fluoroarylation reactions
Based on the recent availability of no-carrier-added (n.c.a.) 1-bromo-4-[F-18]fluorobenzene with high radiochemical yield, the 4[F-18]fluorophenyl compounds of lithium, sodium and magnesium can now also effectively be prepared. Thus, [F-18]fluoroarene reagents with a nucleophilic reaction centre are...
| Personal Name(s): | Ermert, J. |
|---|---|
| Ludwig, T. / Gail, R. / Coenen, H. H. | |
| Contributing Institute: |
Nuklearchemie; INB-4 |
| Published in: | Journal of organometallic chemistry, 692 (2007) S. 4084 - 4092 |
| Imprint: |
New York, NY [u.a.]
Elsevier
2007
|
| Physical Description: |
4084 - 4092 |
| DOI: |
10.1016/j.jorganchem.2007.06.009 |
| Document Type: |
Journal Article |
| Research Program: |
Funktion und Dysfunktion des Nervensystems |
| Series Title: |
Journal of Organometallic Chemistry
692 |
| Subject (ZB): | |
| Publikationsportal JuSER |
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| 245 | |a [18F]fluorophenyl organometallics as intermediates of no-carrier-added 18F-fluoroarylation reactions | ||
| 260 | |a New York, NY [u.a.] |b Elsevier |c 2007 | ||
| 300 | |a 4084 - 4092 | ||
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| 520 | |a Based on the recent availability of no-carrier-added (n.c.a.) 1-bromo-4-[F-18]fluorobenzene with high radiochemical yield, the 4[F-18]fluorophenyl compounds of lithium, sodium and magnesium can now also effectively be prepared. Thus, [F-18]fluoroarene reagents with a nucleophilic reaction centre are available and suitable among others for the formation of [18F]fluorophenyl compounds with electron donating substituents in the radiosynthesis of F-18-labelled complex organic structures. For these arylation reactions, however, the presence of macroscopic amounts of a haloarene as co-reactant is necessary with all n.c.a. [F-18]fluorophenyl metallics. The F-18-fluoroarylation was verified for examples of aryl-carbon, -silicon, -sulphur, and -nitrogen bond formation with radiochemical yields of 20-25% related to the starting radioactivity of [18 F]fluoride. (c) 2007 Elsevier B.V. All rights reserved. | ||
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