Description: A comparative study on the separation of radiozirconium via ion-exchange and solvent extraction techniques, with particular reference to the production of 88Zr and 89Zr in proton induced reactions on Yttrium

This title appears in the Scientific Report : 2007

A comparative study on the separation of radiozirconium via ion-exchange and solvent extraction techniques, with particular reference to the production of 88Zr and 89Zr in proton induced reactions on Yttrium

The radiochemical separation of no-carrier-added zirconium from proton irradiated yttrium was studied by two techniques, namely, ion-exchange chromatography using Dowex 50W-X8 and Dowex 21K resins, and solvent extraction using HDEHP and TPPO, the latter reagent being employed for the first time for...

Personal Name(s):	Kandil, S. A.
	Scholten, B. / Saleh, Z. A. / Youssef, A.M. / Qaim, S. M. / Coenen, H. H.
Contributing Institute:	Nuklearchemie; INB-4
Published in:	Journal of radioanalytical and nuclear chemistry, 274 (2007) S. 45 - 52
Imprint:	Dordrecht [u.a.] Springer Science + Business Media B.V 2007
Physical Description:	45 - 52
DOI:	10.1007/s10967-006-6892-2
Document Type:	Journal Article
Research Program:	Funktion und Dysfunktion des Nervensystems
Series Title:	Journal of Radioanalytical and Nuclear Chemistry 274
Subject (ZB):	J
	Publikationsportal JuSER

Please use the identifier: http://dx.doi.org/10.1007/s10967-006-6892-2 in citations.

The radiochemical separation of no-carrier-added zirconium from proton irradiated yttrium was studied by two techniques, namely, ion-exchange chromatography using Dowex 50W-X8 and Dowex 21K resins, and solvent extraction using HDEHP and TPPO, the latter reagent being employed for the first time for separation of radiozirconium from bulk of yttrium. Out of all those techniques, the solvent extraction using TPPO was found to be the best: the separation yield of radiozirconium was > 97%, the time of separation was short, the contamination from the long-lived Y-88 activity was low ( 10 (4)%) and the final product was obtained in the form of oxalate. The production of Zr-89 and Zr-88 of high radionuclidic and chemical purity via irradiation of yttrium targets with protons of energies 12 and 20 MeV, respectively, is described. The experimental yields of the two radionuclides were found to be 28 MBq/mu A center dot h and 1.63 MBq/mu A center dot h, respectively. Each value corresponds to about 80% of the respective theoretical yield.