Description: Point defect dynamics in sodium aluminium hydrides- A combined quasielastic neutron scattering and density functional theory study

This title appears in the Scientific Report : 2007

Point defect dynamics in sodium aluminium hydrides- A combined quasielastic neutron scattering and density functional theory study

Understanding the catalytic role of titanium-based additives on the reversible hydrogenation of complex metal hydrides is an essential step towards developing hydrogen storage materials for the transport sector. Improved bulk diffusion of hydrogen is one of the proposed catalytic effects, and here w...

Personal Name(s):	Shi, Q.
	Voss, J. / Jacobsen, H.S. / Lefmann, K. / Zamponi, M. / Vegge, T.
Contributing Institute:	JCNS; JCNS Streumethoden; IFF-4 Neutronenstreuung; IFF-5
Published in:	Journal of alloys and compounds, 446-447 (2007) S. 446 - 447
Imprint:	Lausanne Elsevier 2007
Physical Description:	446 - 447
DOI:	10.1016/j.jallcom.2007.04.041
Document Type:	Journal Article
Research Program:	Großgeräte für die Forschung mit Photonen, Neutronen und Ionen (PNI) Kondensierte Materie
Series Title:	Journal of Alloys and Compounds 469
Subject (ZB):	J hydrogen storage materials high-energy ball milling neutron scattering electronic band structure localized hydrogen motion
	Publikationsportal JuSER

Please use the identifier: http://dx.doi.org/10.1016/j.jallcom.2007.04.041 in citations.

Understanding the catalytic role of titanium-based additives on the reversible hydrogenation of complex metal hydrides is an essential step towards developing hydrogen storage materials for the transport sector. Improved bulk diffusion of hydrogen is one of the proposed catalytic effects, and here we study hydrogen dynamics in undoped and TiCl3-doped samples of NaAlH4 and Na3AlH6 using a combination of density functional theory calculations and quasielastic neutron scattering. Hydrogen dynamics is found to be limited and mediated by hydrogen vacancies in both alanate phases, requiring an activation in excess of 0.3 eV. Even at 390 K, less than 1% of the hydrogen in NaAlH4 performs long range diffusion, and only localized hydrogen dynamics is observed in Na3AlH6. The effect of the TiCl3 dopant on hydrogen bulk diffusion is found to be negligible. (C) 2007 Elsevier B.V. All rights reserved.