This title appears in the Scientific Report :
2019
Please use the identifier:
http://dx.doi.org/10.1039/C8DT01455H in citations.
Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand
Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand
A neutral heterobimetallic triple-decker stannole complex was prepared by the reaction of an anionic ruthenocene bearing a stannole dianionic ligand with [Rh(cod)Cl]2 (cod = 1,5-cyclooctadiene), and the resulting Ru–Rh complex exhibits an electronic property different from those of the corresponding...
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Personal Name(s): | Saito, Masaichi (Corresponding author) |
---|---|
Matsunaga, Naoki / Hamada, Jumpei / Furukawa, Shunsuke / Minoura, Mao / Wegner, Susann / Barthel, Juri / Janiak, Christoph | |
Contributing Institute: |
Materialwissenschaft u. Werkstofftechnik; ER-C-2 |
Published in: | Dalton transactions, 47 (2018) 27, S. 8892 - 8896 |
Imprint: |
London
Soc.
2018
|
DOI: |
10.1039/C8DT01455H |
PubMed ID: |
29774331 |
Document Type: |
Journal Article |
Research Program: |
Controlling Configuration-Based Phenomena |
Publikationsportal JuSER |
A neutral heterobimetallic triple-decker stannole complex was prepared by the reaction of an anionic ruthenocene bearing a stannole dianionic ligand with [Rh(cod)Cl]2 (cod = 1,5-cyclooctadiene), and the resulting Ru–Rh complex exhibits an electronic property different from those of the corresponding Ru–Ru and Rh–Rh complexes. The Ru–Rh complex can be decomposed in ionic liquids to metal nanoparticles. |