This title appears in the Scientific Report :
2021
Please use the identifier:
http://dx.doi.org/10.1002/adts.202000319 in citations.
Please use the identifier: http://hdl.handle.net/2128/27404 in citations.
The Influence of Photo‐Induced Space Charge and Energetic Disorder on the Indoor and Outdoor Performance of Organic Solar Cells
The Influence of Photo‐Induced Space Charge and Energetic Disorder on the Indoor and Outdoor Performance of Organic Solar Cells
Apart from traditional large‐scale outdoor application, organic solar cells are also of interest for powering small, off‐grid electronic devices indoors. For operation under the low light intensities that are typical for indoor application, a high shunt resistance is required calling for thick activ...
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Personal Name(s): | Beuel, Sebastian |
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Hartnagel, Paula / Kirchartz, Thomas (Corresponding author) | |
Contributing Institute: |
Photovoltaik; IEK-5 |
Published in: | Advanced theory and simulations, 4 (2021) 3, S. 2000319 |
Imprint: |
Weinheim
Wiley-VCH Verlag
2021
|
DOI: |
10.1002/adts.202000319 |
Document Type: |
Journal Article |
Research Program: |
Photovoltaik und Windenergie |
Link: |
OpenAccess |
Publikationsportal JuSER |
Please use the identifier: http://hdl.handle.net/2128/27404 in citations.
Apart from traditional large‐scale outdoor application, organic solar cells are also of interest for powering small, off‐grid electronic devices indoors. For operation under the low light intensities that are typical for indoor application, a high shunt resistance is required calling for thick active layers in industrial processing to ensure maximum coverage. However, the thickness of an organic solar cell based on energetically disordered semiconductors is limited by space‐charge effects from charged shallow defects under nonuniform generation. While other sources of space charge such as doping and asymmetric transport have been extensively discussed in previous studies, this work offers a theoretical analysis of this photo‐induced space charge in shallow defects and visualizes how the space charge builds up with increasing light intensity with drift‐diffusion simulations. It is shown that the effect particularly deteriorates the performance of an organic solar cell with high active‐layer thickness and substantial energetic disorder. However, the simulations reveal that solar cells are less sensitive to these parameters under low light intensities due to a reduced density of photo‐induced space charge. Therefore, a wider range of material systems and absorber thicknesses can be viable for indoor applications than one may initially expect from testing under 1 sun illumination. |