The Positive Muon as a Probe in Free Radical Chemistry [E-Book] : Potential and Limitations of the μSR Techniques / by E. Roduner.
The work presented here is a result of an extended collaboration with a number of coworkers and guests. Particularly, I would like to thank Dr. P. Burkhard and Dr. W. Strub for their careful work performed for their Ph. D. thesis and Dr. M. Heming for his brilliant ideas and his dedication. Very fru...
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Full text |
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Personal Name(s): | Roduner, E., author |
Imprint: |
Berlin, Heidelberg :
Springer,
1988
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Physical Description: |
VII, 104 p. 1 illus. online resource. |
Note: |
englisch |
ISBN: |
9783642517204 |
DOI: |
10.1007/978-3-642-51720-4 |
Series Title: |
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Lecture Notes in Chemistry ;
49 |
Subject (LOC): |
- 1 Introduction
- 1.1 Motivation
- 1.2 History and properties of the muon and its bound states
- 1.3 The muon as a probe in matter
- 2 Experiments employing muons
- 2.1 Muon production and decay
- 2.2 The ?SR techniques
- 2.3 Analysis and interpretation of the data
- 3 Theory
- 3.1 Hamiltonians, eigenvectors and energies
- 3.2 Evolution of spin polarization
- 4 The cyclohexadienyl radical
- 4.1 Observation in the liquid phase
- 4.2 Observation in other phases
- 4.3 Structure and hyperfine couplings
- 5 Substituent effects on hyperfine coupling constants
- 5.1 Monosubstituted radicals
- 5.2 Comparison with data for benzyl
- 5.3 Polysubstituted radicals
- 6 The process of radical formation
- 6.1 Routes to the cyclohexadienyl radical
- 6.2 Radical formation in cyclohexane solution
- 6.3 Selectivity in mixtures of benzene and dimethylbutadiene
- 6.4 Scavenging experiments
- 7 Distribution of muons in substituted benzenes
- 7.1 Monosubstituted benzenes
- 7.2 Polysubstituted benzenes
- 8 Radical reactions
- 8.1 Secondary isotope effects
- 8.2 Electron transfer reactions
- 8.3 Abstraction reactions
- 8.4 Spin exchange reactions
- 8.5 Transfer of bound Mu, an example for a primary kinetic isotope effect
- 9 Summary and review
- 9.1 Objective
- 9.2 The requirements for the observation of muonated radicals
- 9.3 The different types of radicals observed in liquids
- 9.4 Observations in other phases
- 9.5 Investigation of isotope effects
- 9.6 Investigation of early events
- 9.7 Investigation of radical kinetics
- 9.8 Conclusion.