Principles of Organometallic Chemistry [E-Book] / by G. E. Coates, M. L. H. Green, P. Powell, K. Wade.
The second edition of Organometallic Compounds (1960) was used not only by specialists but also as an undergraduate textbook. The third edition, recently published in two volumes, is about three times the length of the second and contains considerably more factual material than is appropriate for a...
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Full text |
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Personal Name(s): | Coates, G. E., author |
Green, M. L. H., author / Powell, P., author / Wade, K., author | |
Imprint: |
Dordrecht :
Springer Netherlands,
1968
|
Physical Description: |
XII, 258 p. online resource. |
Note: |
englisch |
ISBN: |
9789401096812 |
DOI: |
10.1007/978-94-010-9681-2 |
Subject (LOC): |
- 1. General Survey
- Historical background
- Properties
- Classification of organometallic compounds by bond type
- Covalent, two-centre, two-electron bonds
- Ionic organometallic compounds
- Electron-deficient (multicentre bonded) compounds
- Cluster compounds
- Occurrence of bond type in organo-transition metal complexes
- Availability of electron orbitals in metals and metalloids
- The stability of organometallic compounds
- 2. Methods of Formation of Metal-Carbon Bonds of the Main Group Elements
- The reaction between a metal and an organic halogen compound
- Metal exchange:—the reaction between a metal and an organometallic compound of another metal
- Reactions of organometallic compounds with metal halides
- Insertion of olefins and acetylenes into metal-hydrogen bonds
- Formation of metal-carbon bonds by other insertion reactions
- Reactions of diazo compounds
- Decarboxylation of heavy B-metal salts
- Mercuration and thallation of aromatic compounds
- Mercuration of olefins and acetylenes
- 3. Organometallic Compounds of Elements of the First Three Periodic Groups
- Structural aspects of the metal alkyls
- Preparative aspects
- 4. Organometallic Compounds of Elements of Main Groups IV and V
- Group IVB elements
- Silicones
- Group VB elements
- 5. Organometallic Compounds of the d-Block Transition Elements: Classification of Ligands and Theories of Bonding
- Classification of ligands
- The 18-electron rule
- Bonding in organometallic ?-complexes
- The bonding of other unsaturated hydrocarbons to transition metals
- 6. Preparation of Organo-Transition Metal Compounds
- General considerations
- Preparative routes
- Substitution by organometallic derivatives of main group elements
- Substition using organometallic derivatives of the transition elements : ligand transfer
- From complex transition metal anions and halides
- Unexpected products
- 7. Reactions and Structures of Organometallic Compounds of the Transition Elements
- One-electron ligands
- Two-electron ligands
- Three-electron ligands: ?-allyl and ?-enyl complexes
- Four electron (diene) ligands
- Five-electron (dienyl) ligands
- Six-electron ligands
- Transition metal complexes containing ?-bonded heterocyclic ligands
- Seven-electron ligands
- Cyclo-octatetraene complexes
- 8. The Organic Chemistry of Ferrocene and Related Compounds
- The aromatic character of cyclic CnHn ligands in transition metal complexes
- Aromatic properties of co-ordinated ligands
- Some mechanisms of electrophilic substitution
- Some particular reactions
- The interaction of the iron atom with ring substituents: ?-carbonium ion stabilization
- 9. Organometallic Complexes Formed from Acetylenes
- Mono-acetylene complexes
- Bisacetylene mononuclear complexes
- Trisacetylene complexes
- 10. The Role of Organotransition Metal Complexes in Some Catalytic Reactions
- Olefin isomerisation
- Homogeneous hydrogenation of olefins
- The oxidation of ethylene to acetaldehyde
- The trimerization of butadiene and related reactions catalyzed by some ?-allyl metal complexes
- Hydroformylation and related carbonylation reactions
- Catalytic conversation of acetylenes to ?? unsaturated acids in the presence of nickel carbonyl (Reppe process)
- Vitamin B12 chemistry and related topics
- Nitrogen fixation.