This title appears in the Scientific Report :
2010
Please use the identifier:
http://dx.doi.org/10.1039/C0SC00264J in citations.
Following the self assembly of supramolecular MOFs using X-ray crystallography and cryospray mass spectrometry
Following the self assembly of supramolecular MOFs using X-ray crystallography and cryospray mass spectrometry
We describe the ligand directed self assembly of two mesoscopic supramolecular MOF architectures based upon the rigid ligand cis, trans-1,3,5-triaminocyclohexane with copper(II) salts. The use of copper fluoride results in the assembly of an unprecedented cubic 3D network with 1 nm void spaces while...
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Personal Name(s): | Seeber, G. |
---|---|
Cooper, G.J.T. / Newton, G.N. / Rosnes, M.H. / Long, D.-L. / Kariuki, B.M. / Kögerler, P. / Cronin, L. | |
Contributing Institute: |
Elektronische Eigenschaften; IFF-9 JARA-FIT; JARA-FIT |
Published in: | Chemical engineering science, 1 (2010) S. 62 - 67 |
Imprint: |
Amsterdam [u.a.]
Elsevier Science
2010
|
Physical Description: |
62 - 67 |
DOI: |
10.1039/C0SC00264J |
Document Type: |
Journal Article |
Research Program: |
Grundlagen für zukünftige Informationstechnologien |
Series Title: |
Chemical Engineering Science
1 |
Subject (ZB): | |
Publikationsportal JuSER |
We describe the ligand directed self assembly of two mesoscopic supramolecular MOF architectures based upon the rigid ligand cis, trans-1,3,5-triaminocyclohexane with copper(II) salts. The use of copper fluoride results in the assembly of an unprecedented cubic 3D network with 1 nm void spaces while the use of copper sulfate yields a hexagonal 3D layered network containing nanotubes which are 1.5 nm in diameter. Further, experiments probing the self assembly of the structures after complexation using cryospray mass spectrometry show it is possible to follow the nucleation events that lead to the supramolecular MOFs, and this opens up a new avenue for the direct observation and control of the assembly of complex inorganic architectures. |