This title appears in the Scientific Report :
2015
Please use the identifier:
http://dx.doi.org/10.1039/C4CC09271F in citations.
Please use the identifier: http://hdl.handle.net/2128/22903 in citations.
An Ir IV -containing polyoxometalate
An Ir IV -containing polyoxometalate
[HIrIVW6O24]7−, representing the first Ir-containing Anderson–Evans-type polyanion and the first structurally characterized IrIV-based polyoxometalate, has been isolated as its hydrated sodium salt and characterized by single-crystal X-ray diffraction, mass spectrometry, and IR, UV-Vis and EPR spect...
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Personal Name(s): | Adonin, Sergey A. |
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Izarova, Natalya V. / Besson, Claire / Abramov, Pavel A. / Santiago-Schübel, Beatrix / Kögerler, Paul (Corresponding Author) / Fedin, Vladimir P. / Sokolov, Maxim N. | |
Contributing Institute: |
Analytik; ZEA-3 Elektronische Eigenschaften; PGI-6 |
Published in: | Chemical communications, 51 (2015) 7, S. 1222 - 1225 |
Imprint: |
Cambridge
Soc.
2015
|
DOI: |
10.1039/C4CC09271F |
PubMed ID: |
25469664 |
Document Type: |
Journal Article |
Research Program: |
Addenda |
Link: |
OpenAccess OpenAccess |
Publikationsportal JuSER |
Please use the identifier: http://hdl.handle.net/2128/22903 in citations.
[HIrIVW6O24]7−, representing the first Ir-containing Anderson–Evans-type polyanion and the first structurally characterized IrIV-based polyoxometalate, has been isolated as its hydrated sodium salt and characterized by single-crystal X-ray diffraction, mass spectrometry, and IR, UV-Vis and EPR spectroscopy. Cyclic voltammetry indicates that the IrIV ions in [HIrW6O24]7− can undergo reversible one-electron reduction and oxidation, resulting in IrIII and IrV derivatives. |