This title appears in the Scientific Report :
2001
Please use the identifier:
http://dx.doi.org/10.1351/pac200072112149 in citations.
Localization and bandwidth of the 3d-orbitals in magnetic Ni and Co clusters
Localization and bandwidth of the 3d-orbitals in magnetic Ni and Co clusters
Photoelectron spectra of negatively charged Ni-n(-), Cu-n(-), and Co-n(-) clusters are presented. The spectra of the Ni-n(-) clusters contain information about the degree of localization of the 3d valence orbitals, which is strongly related to the magnetic properties. In the clusters with less than...
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Personal Name(s): | Morenzin, J. |
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Kietzmann, H. / Bechthold, P. S. / Gantefoer, G. / Eberhardt, W. | |
Contributing Institute: |
Elektronische Eigenschaften; IFF-IEE |
Published in: | Pure and applied chemistry, 72 (2001) S. 2149 |
Imprint: |
Research Triangle Park, NC
IUPAC Science
2001
|
Physical Description: |
2149 |
DOI: |
10.1351/pac200072112149 |
Document Type: |
Journal Article |
Research Program: |
Elektronische Struktur von Festkörpern, Oberflächen und Schichtsystemen |
Series Title: |
Pure and Applied Chemistry
72 |
Subject (ZB): | |
Publikationsportal JuSER |
Photoelectron spectra of negatively charged Ni-n(-), Cu-n(-), and Co-n(-) clusters are presented. The spectra of the Ni-n(-) clusters contain information about the degree of localization of the 3d valence orbitals, which is strongly related to the magnetic properties. In the clusters with less than 7 atoms, the 3d orbitals seem to be almost totally localized. For Co-13(-) we find indications of a narrowing of the 3d-derived valence "bandwidth" corresponding to a presumed high symmetry and a high degree of degeneracy of the 3d electronic states. |