This title appears in the Scientific Report :
2015
Please use the identifier:
http://dx.doi.org/10.1002/pssb.201552076 in citations.
A general and Eu specific perspective on lattice dynamics in pyrochlore and defect fluorite (Eu$_{1−x}$Nd$_{x}$)$_{2}$Zr$_{2}$O$_{7}$
A general and Eu specific perspective on lattice dynamics in pyrochlore and defect fluorite (Eu$_{1−x}$Nd$_{x}$)$_{2}$Zr$_{2}$O$_{7}$
Lattice dynamics in pyrochlore and defect fluorite type (Euinline imageNdinline image)inline imageZrinline imageOinline image were investigated using nuclear inelastic scattering by the inline imageEu Mössbauer resonance for x = 0, 0.5, and 0.75 and using inelastic neutron scattering for x = 1. On t...
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Personal Name(s): | Klobes, Benedikt (Corresponding author) |
---|---|
Finkeldei, Sarah / Brandt, Felix / Bosbach, Dirk / Bessas, Dimitrios / Embs, Jan-Peter / Hermann, Raphael | |
Contributing Institute: |
Streumethoden; JCNS-2 Nukleare Entsorgung; IEK-6 JARA-FIT; JARA-FIT Streumethoden; PGI-4 |
Published in: | Physica status solidi / B, 252 (2015) 9, S. 1940 - 1645 |
Imprint: |
Weinheim
Wiley-VCH
2015
|
DOI: |
10.1002/pssb.201552076 |
Document Type: |
Journal Article |
Research Program: |
Jülich Centre for Neutron Research (JCNS) Materials and Processes for Energy and Transport Technologies Quantum Condensed Matter: Magnetism, Superconductivity Controlling Collective States Controlling Collective States |
Publikationsportal JuSER |
Lattice dynamics in pyrochlore and defect fluorite type (Euinline imageNdinline image)inline imageZrinline imageOinline image were investigated using nuclear inelastic scattering by the inline imageEu Mössbauer resonance for x = 0, 0.5, and 0.75 and using inelastic neutron scattering for x = 1. On the basis of the generalized density of phonon states obtained by inelastic neutron scattering, the vibrational entropy of the disordered defect fluorite Ndinline imageZrinline imageOinline image is found to be 12(3)% smaller than the one of the ordered pyrochlore counterpart. Accordingly, the loss of specific Zr–O coordination in the defect fluorite structure leads to a strong broadening of phonon modes. The Eu sublattice in both structure types was further characterized by thermodynamic quantities calculated using the Eu partial density of phonon states. The Eu framework is shown to be significantly softer than the other sublattices. |