This title appears in the Scientific Report :
2001
Please use the identifier:
http://hdl.handle.net/2128/1303 in citations.
Please use the identifier: http://dx.doi.org/10.1063/1.1348032 in citations.
On the non-Gaussianity of chain motion in unentangled polymer melts
On the non-Gaussianity of chain motion in unentangled polymer melts
We have investigated chain dynamics of an unentangled polybutadiene melt via molecular dynamics simulations and neutron spin echo experiments. Good short-time statistics allows for the first experimental confirmation of subdiffusive motion of polymer chains for times less than the Rouse time (tau (R...
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Personal Name(s): | Smith, G. D. |
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Paul, W. / Monkenbusch, M. / Richter, D. | |
Contributing Institute: |
Neutronenstreuung; IFF-NST |
Published in: | The @journal of chemical physics, 114 (2001) S. 4285 - 4288 |
Imprint: |
Melville, NY
American Institute of Physics
2001
|
Physical Description: |
4285 - 4288 |
DOI: |
10.1063/1.1348032 |
Document Type: |
Journal Article |
Research Program: |
Polymere, Membranen und komplexe Flüssigkeiten |
Series Title: |
Journal of Chemical Physics
114 |
Subject (ZB): | |
Link: |
OpenAccess |
Publikationsportal JuSER |
Please use the identifier: http://dx.doi.org/10.1063/1.1348032 in citations.
We have investigated chain dynamics of an unentangled polybutadiene melt via molecular dynamics simulations and neutron spin echo experiments. Good short-time statistics allows for the first experimental confirmation of subdiffusive motion of polymer chains for times less than the Rouse time (tau (R)) confirming behavior in this regime observed in simulations. Analysis of simulation trajectories obtained over several Rouse times reveals non-Gaussian segmental displacements for all time and length scales. These results, particularly non-Gaussian displacements on large time- and length scales, demonstrate the importance of intermolecular correlations on chain dynamics. Rouse-type analytical models fail to account for this non-Gaussianity leading to large deviations between the experimental dynamic structure factor and model predictions. (C) 2001 American Institute of Physics. |