Description: Removing compositional boundaries in mixed-linker Keplerate clusters

This title appears in the Scientific Report : 2009

Removing compositional boundaries in mixed-linker Keplerate clusters

The formation of a self-assembled multi-heterometal Keplerate polyoxomolybdate demonstrates compositional control of linker groups in spherical clusters. The resulting partially reduced {(Mo72Fe20V8Mo2V)-Fe-V/VI-V-III-Mo-IV}-type cluster exhibits intramolecular ferrimagnetic ordering characteristic...

Personal Name(s):	Botar, B.
	Ellern, A. / Hermann, R. / Kögerler, P.
Contributing Institute:	Elektronische Eigenschaften; IFF-9 JARA-FIT; JARA-FIT
Published in:	European journal of inorganic chemistry, 2009 (2009) S. 5071 - 5074
Imprint:	Weinheim Wiley-VCH 2009
Physical Description:	5071 - 5074
DOI:	10.1002/ejic.200900638
Document Type:	Journal Article
Research Program:	Grundlagen für zukünftige Informationstechnologien
Series Title:	European Journal of Inorganic Chemistry 7
Subject (ZB):	J Cluster compounds Molybdenum Iron Vanadium Polyoxometalates Metal-metal interactions Molecular magnetism
	Publikationsportal JuSER

Please use the identifier: http://dx.doi.org/10.1002/ejic.200900638 in citations.

The formation of a self-assembled multi-heterometal Keplerate polyoxomolybdate demonstrates compositional control of linker groups in spherical clusters. The resulting partially reduced {(Mo72Fe20V8Mo2V)-Fe-V/VI-V-III-Mo-IV}-type cluster exhibits intramolecular ferrimagnetic ordering characteristic of such mixed-spin Keplerate systems. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)