This title appears in the Scientific Report :
2016
Please use the identifier:
http://hdl.handle.net/2128/13210 in citations.
Please use the identifier: http://dx.doi.org/10.1002/chem.201604238 in citations.
Classical/Non-classical Polyoxometalate Hybrids
Classical/Non-classical Polyoxometalate Hybrids
Two polyanions [SeI V2PdII4WVI14O56H]11− and [SeI V4PdII4WVI28O108H12]12− are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and non-classical (late transition-metal based) polyoxometalate units are joined. Requiring no supporting groups, this co-condensation of polyoxo...
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Personal Name(s): | Izarova, Natalya V. (Corresponding author) |
---|---|
Santiago-Schübel, Beatrix / Willbold, Sabine / Hess, Volkmar / Kögerler, Paul | |
Contributing Institute: |
Analytik; ZEA-3 Elektronische Eigenschaften; PGI-6 |
Published in: | Chemistry - a European journal, 22 (2016) 45, S. 16052 - 16056 |
Imprint: |
Weinheim
Wiley-VCH
2016
|
PubMed ID: |
27617918 |
DOI: |
10.1002/chem.201604238 |
Document Type: |
Journal Article |
Research Program: |
Addenda |
Link: |
OpenAccess OpenAccess |
Publikationsportal JuSER |
Please use the identifier: http://dx.doi.org/10.1002/chem.201604238 in citations.
Two polyanions [SeI V2PdII4WVI14O56H]11− and [SeI V4PdII4WVI28O108H12]12− are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and non-classical (late transition-metal based) polyoxometalate units are joined. Requiring no supporting groups, this co-condensation of polyoxotungstate and isopolyoxopalladate constituents also provides a logical link between POM-PdII coordination complexes and the young subclass of polyoxopalladates. Solid-state, solution, and gas-phase studies suggest interesting specific reactivities for these hybrids and point to several potential derivatives and functionalization strategies. |