This title appears in the Scientific Report :
2022
Please use the identifier:
http://dx.doi.org/10.1002/pip.3517 in citations.
Please use the identifier: http://hdl.handle.net/2128/31056 in citations.
Accelerated lifetime testing of thin‐film solar cells at high irradiances and controlled temperatures
Accelerated lifetime testing of thin‐film solar cells at high irradiances and controlled temperatures
Within this study, we investigate the intrinsic photostability of thin-film solar cells,here organic photovoltaic cells. Since degradation under natural sun light proceedswithin the timeframe of months and years, the process needs to be speeded up forfast material analysis and screening, using high-...
Saved in:
Personal Name(s): | Burlafinger, Klaus |
---|---|
Strohm, Sebastian / Joisten, Christoph / Woiton, Michael / Classen, Andrej / Hepp, Johannes (Corresponding author) / Heumüller, Thomas / Brabec, Christoph / Vetter, Andreas | |
Contributing Institute: |
Helmholtz-Institut Erlangen-Nürnberg Erneuerbare Energien; IEK-11 |
Published in: | Progress in photovoltaics, 30 (2022) 5, S. 518-527 |
Imprint: |
Chichester
Wiley
2022
|
DOI: |
10.1002/pip.3517 |
Document Type: |
Journal Article |
Research Program: |
Design, Operation and Digitalization of the Future Energy Grids Simulations, Theory, Optics, and Analytics (STOA) Modules, stability, performance and specific applications Cell Design and Development Materials and Interfaces Digitalization and Systems Technology for Flexibility Solutions |
Link: |
OpenAccess |
Publikationsportal JuSER |
Please use the identifier: http://hdl.handle.net/2128/31056 in citations.
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520 | |a Within this study, we investigate the intrinsic photostability of thin-film solar cells,here organic photovoltaic cells. Since degradation under natural sun light proceedswithin the timeframe of months and years, the process needs to be speeded up forfast material analysis and screening, using high-concentration accelerated lifetimetesting (high-C ALT). For this purpose, we established setups allowing irradiances ofup to 730 sun equivalents (SE). One key finding of our study is that accelerating thetesting procedure by such large intensities is possible but a precise measurement andcontrol of the solar cell temperature is absolutely essential. Accordingly, we devel-oped an innovative method of determining the temperature of the active layer whichoffers significant advantages over commonly used measurement methods. Further-more, it was found that the degradation process under high illumination densities canbe well described by a stretched exponential law. We demonstrate that the tempera-ture kinetics of P3HT:PCBM was found to be Arrhenius governed with an activationenergy of 27.2 kJ/mol under continuous illumination of 300 SE. Finally, it was shownthat the velocity of light-induced degradation of short-circuit current depends line-arly on the used irradiance dose at a given temperature starting from normal illumina-tion conditions up to at least 300 SE. This makes high-C ALT a very valuable tool forswift screening of the lifetime of novel thin-film solar cells and materials. | ||
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